Ko te trifluoromethanesulfonic anhydride, e mohiotia ana ko te triflic anhydride, ko te pūhui matū me te tātai₂O.
Ko te waikawa anhydride i ahu mai i te waikawa triflic.
Ko tenei puhui he electrophile kaha, he pai mo te whakauru i te roopu triflyl, CF₃SO₂.
Ko te Tf₂O whakapoto, triflic anhydride ko te waikawa anhydride o te waikawa triflic acid kaha, CF₃SO₂OH.
Nga taonga | Whakatakotoranga | Nga hua whakamatautau |
Te ahua | Te wai marama kore tae | Ka rite |
Maamaa | 99.0% min | 99.52% |
F | ≤50ppm | 13.9ppm |
CF3SO3H | ≤0.5% | 0.38% |
SO4 | ≤100ppm | 74.4ppm |
Whakamutunga: Tohu. |
Ko te Trifluoromethanesulfonic Anhydride he electrophile kaha e whakamahia ana i roto i te whakahiato matū mo te whakauru i te roopu triflyl.
Ka whakamahia te trifluoromethanesulfonic anhydride ki te huri i nga phenols me te imine ki roto i te ester triflic me te roopu NTf. He electrophile kaha e whakamahia ana mo te whakauru i te roopu triflyl i roto i te whakahiato matū. Ka mahi hei reagent i roto i te whakarite o te alkyl me te vinyl triflates, me te whakahiato stereosective o te mannosazide methyl uronate donors. Ka mahi hei whakakorikori mo te glycosylation me nga huka hauwai anomeric hei whakarite i nga polysaccharides.
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